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High schoolConstitution of matter11 minLesson 3 of 33

Periodic classification

Reading the periodic table: groups, periods, s/p/d/f blocks. Families, metals/non-metals/metalloids.

How the periodic table is organized

The periodic table arranges all 118 known elements in order of increasing atomic number Z. This arrangement reveals a striking periodicity of physical and chemical properties.

  • A period (horizontal row) corresponds to a principal energy level n. Period 1 holds H and He (filling the 1s shell). Period 4 starts with K (4s filling) and includes the first row of transition metals (3d filling).
  • A group (vertical column) groups elements with the same valence configuration and therefore similar chemical behavior. Groups are numbered 1–18.
General structure of the periodic table: periods and groups
General structure of the periodic table: periods and groups

The four blocks

The block an element belongs to is determined by which subshell is being filled last:

BlockSubshellGroupsExamples
sns1–2H, Li, Na, Mg, Ca
pnp13–18C, N, O, F, Cl, Ne
d(n−1)d3–12Fe, Cu, Zn, Ti
f(n−2)fLanthanides / ActinidesCe, U

Lanthanides (Z = 57–71) and actinides (Z = 89–103) are placed separately at the bottom of the table for practical layout reasons.

Key families

Several groups carry traditional names:

  • Group 1 — Alkali metals: Li, Na, K, Rb, Cs, Fr. One valence electron (ns¹). Highly reactive; react vigorously with water.
  • Group 2 — Alkaline-earth metals: Be, Mg, Ca, Sr, Ba, Ra. Configuration ns².
  • Group 17 — Halogens: F, Cl, Br, I, At. Seven valence electrons (ns² np⁵). Readily form X⁻ anions.
  • Group 18 — Noble gases: He, Ne, Ar, Kr, Xe, Rn. Full valence shell; very low reactivity.

Metals, non-metals, and metalloids

The table divides into three broad zones:

Metals (left and center): shiny, good conductors of heat and electricity, malleable. About 75 % of all elements are metals (e.g. Na, Fe, Au).

Non-metals (upper right): often gaseous at room temperature, poor conductors (e.g. H, C, N, O, S). They form covalent bonds with each other and with metals.

Metalloids (diagonal boundary): intermediate properties, often semiconductors (B, Si, Ge, As, Sb, Te). Critical in electronics.

Metals / metalloids / non-metals zones
Metals / metalloids / non-metals zones

Locating an element from Z

Given Z, you can identify the period and group without memorizing the whole table:

  • Chlorine (Z = 17): [Ne] 3s² 3p⁵ → period 3, group 17 (halogen).
  • Iron (Z = 26): [Ar] 4s² 3d⁶ → period 4, group 8 (transition metal).
  • Germanium (Z = 32): [Ar] 4s² 3d¹⁰ 4p² → period 4, group 14 (metalloid).

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