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H₂O

Water

IUPAC : Water
OtherEverydayBiologicalIndustrialLaboratory

Bent triatomic molecule, universal solvent and dominant component of the biosphere. Its anomalous properties (density maximum at 4 °C, high surface tension, high specific heat) arise from hydrogen bonding between molecules.

3D ball-and-stick representation of Water (formula H₂O). Constituent atoms: H, O.
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Physical properties

Molar mass18.01528 g/mol
State at 20 °Cliquid
Density1 g/cm³
Melting point273.15 K (0.00 °C)
Boiling point373.15 K (100 °C)
Solubility (H₂O)miscible (solvant)
Refractive index1.333

Structure

Crystal system
3D render modeBall-and-stick

Detailed description

Water is the most studied molecule in chemistry, yet remains the one that most defies simple expectations. Its polarity — oxygen pulls strongly on the electrons of both O–H bonds — produces intermolecular hydrogen bonds that structure the liquid far more than a simple 18 g/mol gas would suggest (at comparable mass, methane CH₄ boils at −161 °C; water, at +100 °C). This dynamic network explains its unique ability to dissolve ions and polar molecules while remaining inert toward fats — the hydrophilic/hydrophobic dichotomy underlying all biochemistry.

The best-known anomaly is its density maximum at 4 °C: cooled below that, water expands because hydrogen bonds force it into an open lattice (ice floats). Without this inversion, lakes would freeze from the bottom up and aquatic life in temperate climates would be impossible. The high specific heat (4.18 J·g⁻¹·K⁻¹) also buffers the planet's climate: oceans absorb and release thermal energy with an inertia that smooths seasonal swings.

Historically, water was considered an element for two millennia — from Empedocles' four elements to the late 18th century. Antoine Lavoisier demonstrated in 1783, by decomposing it at high temperature and then recombining hydrogen and oxygen, that it is in fact a compound — a result that marks the transition from alchemical to modern chemistry. The official IUPAC name, oxidane, never entered common usage.

Where it is found

Oceans, glaciers, atmosphere (vapour, clouds), biological tissues (~60 % of human body mass), comets and icy moons of the outer solar system.

Uses and applications

  • Biological and laboratory solvent
  • Heat transfer fluid (power plants, heating)
  • Washing and extraction agent
  • Reagent in green chemistry (hydrolysis, hydration)

Constituent elements

References

PubChem CID962
CAS7732-18-5
SMILESO
InChIInChI=1S/H2O/h1H2
InChI KeyXLYOFNOQVPJJNP-UHFFFAOYSA-N

Related processes

Industrial processes involving this compound.