Water
Bent triatomic molecule, universal solvent and dominant component of the biosphere. Its anomalous properties (density maximum at 4 °C, high surface tension, high specific heat) arise from hydrogen bonding between molecules.
Physical properties
Structure
Detailed description
Water is the most studied molecule in chemistry, yet remains the one that most defies simple expectations. Its polarity — oxygen pulls strongly on the electrons of both O–H bonds — produces intermolecular hydrogen bonds that structure the liquid far more than a simple 18 g/mol gas would suggest (at comparable mass, methane CH₄ boils at −161 °C; water, at +100 °C). This dynamic network explains its unique ability to dissolve ions and polar molecules while remaining inert toward fats — the hydrophilic/hydrophobic dichotomy underlying all biochemistry.
The best-known anomaly is its density maximum at 4 °C: cooled below that, water expands because hydrogen bonds force it into an open lattice (ice floats). Without this inversion, lakes would freeze from the bottom up and aquatic life in temperate climates would be impossible. The high specific heat (4.18 J·g⁻¹·K⁻¹) also buffers the planet's climate: oceans absorb and release thermal energy with an inertia that smooths seasonal swings.
Historically, water was considered an element for two millennia — from Empedocles' four elements to the late 18th century. Antoine Lavoisier demonstrated in 1783, by decomposing it at high temperature and then recombining hydrogen and oxygen, that it is in fact a compound — a result that marks the transition from alchemical to modern chemistry. The official IUPAC name, oxidane, never entered common usage.
Oceans, glaciers, atmosphere (vapour, clouds), biological tissues (~60 % of human body mass), comets and icy moons of the outer solar system.
Uses and applications
- Biological and laboratory solvent
- Heat transfer fluid (power plants, heating)
- Washing and extraction agent
- Reagent in green chemistry (hydrolysis, hydration)
Constituent elements
References
Related processes
Industrial processes involving this compound.
- Nuclear energyInput
Pressurized Water Reactor (PWR)
The most widely deployed nuclear reactor design in the world (~70 % of the fleet). Primary-loop water, pressurized to 155 bar to stay liquid at 320 °C, carries fission heat from UO₂ fuel to a steam generator that feeds the turbine.
- ElectrolysisInput
Chlor-alkali process
Electrolysis of brine (NaCl) into chlorine (Cl₂), caustic soda (NaOH) and hydrogen (H₂) in a single process. Cornerstone of mineral chemistry — world production ~85 Mt Cl₂/year and ~80 Mt NaOH/year.
- Nuclear energyInput
Boiling Water Reactor (BWR)
Direct-cycle nuclear reactor: core water boils at 285 °C / 70 bar to produce the steam that drives the turbine directly, without a secondary loop. ~70 reactors in service (~25 % of the world fleet), mainly in the United States, Japan and Sweden.