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UO₂

Uranium dioxide

IUPAC : Uranium dioxide
OxideIndustrialMineral/geological

The most widely used nuclear fuel worldwide. Sintered ceramic pellets (~1 cm × 1 cm) clad in zirconium alloy, assembled into rods and then fuel assemblies — this is what fissions in the core of PWR, BWR and EPR reactors.

3D ball-and-stick representation of Uranium dioxide (formula UO₂). Constituent atoms: U, O.
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Physical properties

Molar mass270.028 g/mol
State at 20 °Csolid
Density10.97 g/cm³
Melting point3140.00 K (2867 °C)
Boiling point3815.00 K (3542 °C)
Solubility (H₂O)insoluble

Structure

Crystal systemCubic
3D render modeBall-and-stick

Uses and applications

  • Light-water reactor fuel (PWR, BWR — ~85 % of the global fleet)
  • MOX fuel (UO₂ + PuO₂ blend) — recycling of plutonium from reprocessing
  • Radioisotope sources for research and instrumentation
  • High-purity nuclear ceramics

Safety (GHS)

GHS06 · Acute toxicityGHS08 · Health hazard (CMR)GHS09 · Environmental hazard
H statements : H300, H330, H373, H411

Chemical toxicity (kidneys) and radioactivity (α emitter). Strictly controlled handling in the closed nuclear cycle. Fissile material subject to non-proliferation.

Constituent elements

References

PubChem CID10916
CAS1344-57-6
Sources : IAEA — Nuclear Fuel Cycle and Materials · OECD/NEA — Trends in the Nuclear Fuel Cycle · PubChem CID 10916

Related processes

Industrial processes involving this compound.