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H₂SO₄

Sulfuric acid

IUPAC : Sulfuric acid
AcidSulfateIndustrialLaboratory

The most produced chemical worldwide by tonnage (>200 Mt/yr). A historical indicator of a country's industrialisation.

3D ball-and-stick representation of Sulfuric acid (formula H₂SO₄). Constituent atoms: H, S, O.
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Physical properties

Molar mass98.079 g/mol
State at 20 °Cliquid
Density1.8302 g/cm³
Melting point283.46 K (10.31 °C)
Boiling point610.15 K (337 °C)
Solubility (H₂O)miscible (fortement exothermique)
pKapKa₁ ≈ −3, pKa₂ = 1.99

Structure

Crystal system
3D render modeBall-and-stick

Detailed description

Sulfuric acid was, for a long time, used as an economic indicator before GDP: its per-capita consumption tracked a country's level of industrialisation closely. This centrality stems from its ubiquity — it intervenes at one stage or another in about half of all modern chemical production chains, without ever appearing as a visible consumer product. About 60 % of world production (~270 Mt/yr) is consumed in superphosphate and ammonium-nitrate fertiliser manufacture, with the rest split between sulfide ore refining, petrochemistry, lead-acid batteries and organic synthesis.

Chemically, H₂SO₄ is a strong diprotic acid with an exceptional affinity for water — so much that it dehydrates sugar, wood or skin in seconds with violent exotherm, leaving a black carbonaceous residue. This property is leveraged as a dehydrating agent in organic synthesis but also explains why handling remains dangerous even at moderate concentration. Concentrated solutions (>96 %) are fuming (oleum) because of dissolved SO₃.

Industrially, the contact process (1831, patented by Peregrine Phillips) remains the global standard. It catalytically oxidises SO₂ to SO₃ over vanadium pentoxide, then absorbs SO₃ in concentrated H₂SO₄ to give oleum, diluted afterwards to the desired strength. The process is globally exothermic: a modern plant recovers 4-6 GJ per tonne of acid as HP steam — making it one of the few industrial processes that is a net energy producer while making a chemical.

Uses and applications

  • Manufacture of phosphate fertilisers (superphosphate, ammonium nitrates)
  • Petroleum refining and metallurgy
  • Lead-acid battery electrolyte
  • Dehydrating reagent in organic synthesis

Safety (GHS)

GHS05 · Corrosive
H statements : H314, H290

Extremely corrosive. Always add acid TO water, never the reverse (risk of splattering).

Constituent elements

References

PubChem CID1118
CAS7664-93-9
SMILESOS(=O)(=O)O

Related processes

Industrial processes involving this compound.