High school9 min

Carbon skeletons: chains, names and isomers

Recognise a saturated, branched or cyclic chain, name a branched alkane without picking the wrong chain, and find the isomers of a molecular formula.

The essentials

1

Saturated or unsaturated

A saturated chain contains only CC\ce{C-C} single bonds: these are the alkanes, of formula CnH2n+2\text{C}_n\text{H}_{2n+2} when they are not cyclic. An unsaturated chain carries at least one C=C\ce{C=C} double bond (alkenes, CnH2n\text{C}_n\text{H}_{2n}) or one CC\ce{C#C} triple bond (alkynes, CnH2n2\text{C}_n\text{H}_{2n-2}). There is no free rotation about a double bond.
2

Linear, branched, cyclic

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3

Roots, suffixes, branches

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4

Structural isomers

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5

Boiling points

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