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72Hf178.486

Hafnium

Transition metalsBlock dPeriod 6Group 4solid at 20 °C
Configuration :
[Xe] 4f¹⁴ 5d² 6s²
Atomic mass :
178.486 u
3D Bohr-model representation of the Hafnium atom (symbol Hf, atomic number Z=72). Electron shell configuration: 2, 8, 18, 32, 10, 2 electrons.
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Electron configuration

Full1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d² 6s²
Short[Xe] 4f¹⁴ 5d² 6s²
Valence electrons4
KLMNOPQ shells
K2
L8
M18
N32
O10
P2

Electronegativity

Pauling1.3
Allen
Mulliken (eV)

Atomic radii

Empirical155 pm
Calculated208 pm
Covalent175 pm
Van der Waals
Ionic radii (Shannon-Prewitt)
+471 pm

Successive ionisation energies

I₁658.5 kJ/mol
I₂1440 kJ/mol
I₃2250 kJ/mol
I₄3216 kJ/mol
Electron affinity17.2 kJ/mol

Oxidation states

-20+1+2+3+4
Bold states = most common.
Period 6Block dIUPAC Group 4Family Transition metals
Sources : NIST Atomic Weights & Isotopic Compositions, IUPAC Recommendations, CODATA. Methodology